Phase-transfer catalyzed formation of cyanohydrin ethers and acetates
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چکیده
منابع مشابه
TBD- or PS-TBD-Catalyzed One-Pot Synthesis of Cyanohydrin Carbonates and Cyanohydrin Acetates from Carbonyl Compounds.
Cyanation reactions of carbonyl compounds with methyl cyanoformate or acetyl cyanide catalyzed by 5 mol % of 1,5,7-triazabicyclo[4,4,0]dec-5-ene (TBD) were examined. Using methyl cyanoformate, the corresponding cyanohydrin carbonates were readily obtained in high yield for aromatic and aliphatic aldehydes and ketones. Similar results were obtained when acetyl cyanide was used as the cyanide sou...
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Domino gold-catalyzed rearrangement and fluorination of propargyl acetates.
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1977
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v77-595